Analysis of Physical and Chemical Parameters for Discrimination of Water Origin in a Hydroelectric Reservoir     

Wagner José Barreto  Ieda Scarminio  Maria Cristina Solci  Dílson Norio Ishikawa  Melissa Tiemi Ogasawara  Sônia Naomi Nomi  Sônia Regina Giancoli Barreto 《洁净——土壤、空气、水》2007,35(3):239-245

Seventeen physical and chemical parameters were obtained from a hydroelectric reservoir located in a tropical region in the south of Brazil. Multivariate Principal Component Analysis (PCA) and Hierarchical Group Analysis (HGA) were used to identify the parameters discriminating the origin of water from the Tibagi and the Primeiro de Maio River, after it has passed the mixing region. The study was conducted during the dry and rainy seasons in July 2002 and February 2003 at three depths and three sampling sites located 0, 5, and 10 km away from the mixing region. The statistical methods showed to be appropriate for identifying the contribution of each tributary in the water mixing site of a complex water system. The most important discriminating parameter was the absorbance relation A(253 nm)/A(203 nm), followed by the concentrations of Fe(III), Mn(III), and Ni(II). An anthropogenic interference was found in the reservoir due to high Ni(II) and orthophosphate concentrations caused by a nearby town sewage discharge. The interference was more important during the dry periods due to the lower dispersion of the pollutants. Urgent initiatives should be taken from the state government to build treatment stations for the wastewater of the small cities around the Capivara hydroelectric reservoir to prevent the drinking water quality from deteriorating.  相似文献   

Fe,Mn, P and S Speciation in Sediments from the Capivara Hydroelectric Dam Lake (Brazil) as an Indicator of Anthropogenic Influences     

Wagner José Barreto  Dilson Norio Ishikawa  Ieda Spacino Scarminio  João de Souza Costa  Paulo dos Santos Nora  Miriam de Fatima Soares  Romilaine Mansano Nicolau  Adriana Celeste Esteves Gonçalves  Sonia Regina Giancoli Barreto 《洁净——土壤、空气、水》2008,36(4):353-359

The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.  相似文献